首页> 外文OA文献 >N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide
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N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-4-fluoro-N-(4-fluoro­benzo­yl)benzamide

机译:N-(3-溴-1,4-二氧代-1,4-二氢-2-萘­基)-4-氟-N-(4-氟­苯­基)苯甲酰胺

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摘要

In the title compound, C24H12BrF2NO4, synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 4-fluoro­benzoyl chloride, the two p-fluoro­phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fluoro­phenyl rings are located opposite each other, connected to the imide group in a funnel-like arrangement. This conformation allows the fluorine groups be oriented slightly away from each other. An examination of the packing shows a close inter­molecular F⋯O contact of 2.982 (5) Å and a Br⋯O contact of 2.977 (4) Å. In addition, the mol­ecules are linked by weak inter­molecular C—H⋯O and C—H⋯F inter­actions.
机译:由2-氨基-3-溴-1,4-萘醌和4-氟苯甲酰氯合成的标题化合物C24H12BrF2NO4中,两个对氟苯环相对于萘醌倾斜73.9(1)和73.6(1)°铃声系统。两个亚氨基羰基O原子彼此相反,而氟代苯基环彼此相对,并以漏斗状排列与亚酰胺基连接。这种构象使得氟基团彼此之间略微远离。检查填料后,发现分子间的F⋯O紧密接触为2.982(5)Å,Br⋯O接触为2.977(4)Å。另外,分子通过弱的分子间CHOH和CHF相互作用相互连接。

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